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Let be the Laplace-Beltrami operator on a non-compact symmetric space of any rank, and denote the bottom of its -spectrum as . In this paper, we provide a comprehensive characterization of both the sufficient and necessary conditions ensuring the validity of the Stein-Weiss inequality for the entire family of operators . As an application, some weighted functional inequalities, such as Heisenberg’s uncertainty principle, Gagliardo-Nirenberg’s interpolation inequality, Pitt’s inequality, etc., become available in this context. In particular, their sets of admissible indices are larger than those in the Euclidean setting.

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