We construct a new solution to the tetrahedron equation and the three-dimensional (3D) reflection equation by extending the quantum cluster algebra approach by Sun and Yagi concerning the former. We consider the Fock-Goncharov quivers associated with the longest elements of the Weyl groups of type and , and investigate the cluster transformations corresponding to changing a reduced expression into a `most distant’ one. By devising a new realization of the quantum -variables in terms of -Weyl algebra, the solutions are extracted as the operators whose adjoint actions yield the cluster transformations of the quantum -variables. Explicit formulas of their matrix elements are also derived for some typical representations.

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