We study Lie bialgebra structures on \emph{flat metric Lie algebras}, that is, Lie algebras whose associated left-invariant Riemannian metric on the simply connected Lie group has zero curvature. By Milnor’s structure theorem, such splits orthogonally as where is the center and is an abelian subalgebra that acts on by commuting infinitesimal rotations; this yields a decomposition of into -dimensional weight planes . Under a generic \emph{nondegeneracy} (nonresonance) condition on the weights, we establish a normal form for Lie-bialgebra -cocycles : each admits a decomposition , where is a coboundary and is a normalized cocycle with tightly controlled components. Using the Big Bracket (Maurer–Cartan) formalism together with the rotation geometry of the weight planes, we split the co-Jacobi condition into two independent equations: a reduced co-Jacobi equation for the normalized cocycle, and an invariant-trivector condition for the coupling term. We then describe the quasi-triangular (classical Yang–Baxter) locus via invariant Schouten squares. Finally, we integrate to explicit multiplicative Poisson tensors on , producing concrete families of flat Poisson–Lie groups with polynomial formulas along the abelian normal subgroup .

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