In this paper, we investigate the geometry of moduli space of degree del Pezzo pair, that is, a del Pezzo surface of degree with a curve . More precisely, we study compactifications for from both Hodge’s theoretical and geometric invariant theoretical (GIT) perspective. We compute the Picard numbers of these compact moduli spaces which is an important step to set up the Hassett-Keel-Looijenga models for . For case, we propose the Hassett-Keel-Looijenga program as the section rings of certain -line bundle on locally symmetric variety , which is birational to . Moreover, we give an arithmetic stratification on . After using the arithmetic computation of pullback on these arithmetic strata, we give the arithmetic predictions for the wall-crossing behavior of when varies. The relation of with the K-moduli spaces of degree del Pezzo pairs is also proposed.

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