This paper studies super -matrices and operator forms of the super classical Yang-Baxter equation. First by a unified treatment, the classical correspondence between -matrices and -operators is generalized to a correspondence between homogeneous super -matrices and homogeneous -operators. Next, by a parity reverse of Lie superalgebra representations, a duality is established between the even and the odd -operators, giving rise to a parity duality among the induced super -matrices. Thus any homogeneous -operator or any homogeneous super -matrix with certain supersymmetry produces a parity pair of super -matrices, and generates an infinite tree hierarchy of homogeneous super -matrices. Finally, a pre-Lie superalgebra naturally defines a parity pair of -operators, and thus a parity pair of super -matrices.

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