Within the framework of an extended quantum molecular dynamics model, we simulated Ca + O collisions at beam energies ranging from 60 to 150 MeV/nucleon for O with different -cluster configurations. Results imply that different -cluster configurations lead to different yields of deuteron, triton, He and He, but not for proton and neutron. We discuss the effect of geometric fluctuations which are presented by double ratios of light nuclei, namely and . It is found that magnitude hierarchy of geometric fluctuations is chain, kite, square and tetrahedron structure of O. has maximum value around 80 – 100 MeV/nucleon which could be related to liquid-gas phase transition, that is consistent with results from the charge distribution of the heaviest fragments in the collisions.

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