We propose a new approach to building log-canonical coordinate charts for any simply-connected simple Lie group and arbitrary Poisson-homogeneous bracket on associated with Belavin–Drinfeld data. Given a pair of representatives from two arbitrary Belavin–Drinfeld classes, we build a rational map from with the Poisson structure defined by two appropriately selected representatives from the standard class to equipped with the Poisson structure defined by the pair . In the case, we prove that this map is invertible whenever the pair is drawn from aperiodic Belavin–Drinfeld data, as defined in~\cite{GSVple}. We further apply this construction to recover the existence of a regular complete cluster structure compatible with the Poisson structure associated with the pair in the aperiodic case.

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