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The set of two-body reduced states of translation invariant, infinite quantum spin chains can be approximated from inside and outside using matrix product states and marginals of finite systems, respectively. These lead to hierarchies of algebraic approximations that become tight only in the limit of infinitely many auxiliary variables. We show that this is necessarily so for any algebraic ansatz by proving that the set of reduced states is not semialgebraic. We also provide evidence that additional elementary transcendental functions cannot lead to a finitary description.

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