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In this letter we analyze the associated production of a vector meson with the bound - free process in ultraperipheral collisions through the double scattering mechanism for the energy of the Large Hadron Collider (LHC). Such process is characterized by the presence of a meson and a positron in the final state and by a forward hydrogen - like ion with a distinct electric charge. We present our predictions for the total cross sections and rapidity distributions considering the rapidity ranges covered by the ALICE and LHCb detectors, which indicate that a future experimental analysis of the and final states is feasible.

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