We study the fluctuation properties of the local time density, , spent by a -dimensional Brownian particle at a spherical shell of unit radius, where denotes the radial distance from the particle to the origin. In the large observation time limit, , the local time density obeys the large deviation principle, , where the rate function is analytic everywhere for . In contrast, for , becomes nonanalytic at a specific point , where depends solely on dimensionality. The singularity signals the occurrence of a first-order dynamical phase transition in dimensions higher than four. Such a transition is accompanied by temporal phase separations in the large deviations of Brownian trajectories. Finally, we validate our theoretical results using a rare-event simulation approach.

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