Neutron skins of neutron-rich nuclei connect nuclei with the matter in neutron stars. High-precision measurements of nuclear charge densities to extract higher-order moments are proposed to be sensitive to neutron radii and skin thicknesses. We investigate the charge density of Ca and Pb, leading candidates for such studies, with ab initio nuclear structure calculations. We find strong correlations between the fourth-order charge density moment and the charge and neutron radii, allowing us to predict for Ca and Pb. We find a substantially weaker correlation between the fourth-order charge density moment and the neutron skin, limiting the ability of high-precision electron scattering to determine the neutron skin in a model-independent manner.

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