The authors of this article intend to present some results obtained in the study of biderivations of complete Lie algebras. Firstly they present a matricial approach to do this, which was a useful and explanatory tool not only in the study of biderivations but also in the synthesis of these results. Then they study all biderivations of a Lie algebra with and , called complete. Moreover, as an application of the previous result, they describe all biderivations of a semisimple Lie algebra (that are complete), extending a result obtained by X. Tang in ([20]) that describes all biderivations of a complex simple Lie algebra. And thirdly, results on symmetric and skew-symmetric biderivations are also presented.

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