In this paper, we prove the existence of families of smooth unbounded domains with , where \begin{equation} Ω_s=\left{(x,t)\in ^N\times :\vert x\vert<1+s\cos \left(\frac{2π}{T(s)}t\right)+s w_s\left(\frac{2π}{T(s)}t\right)\right},\nonumber \end{equation} such that \begin{equation} -Δu=λu,, ,,Ω, ,, \partial_νu=0,,,u=,,,,\partialΩ\nonumber \end{equation} admits a bounded sign-changing solution with exactly nodal domains. These results can be regarded as counterexamples to the Schiffer conjecture on unbounded domain. These results also indicate that there exist non-spherical unbounded regions without Pompeiu property. Our construction shows that the condition “ is homeomorphic to the unit sphere” is necessary for Williams conjecture to hold. In addition, these conclusions may have potential applications in remote sensing or CT.

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