In this paper, we study a priori error estimates for the finite element approximation of the nonlinear Schrödinger-Poisson model. The electron density is defined by an infinite series over all eigenvalues of the Hamiltonian operator. To establish the error estimate, we present a unified theory of error estimates for a class of nonlinear problems. The theory is based on three conditions: 1) the original problem has a solution which is the fixed point of a compact operator , 2) is Fréchet-differentiable at and has a bounded inverse in a neighborhood of , and 3) there exists an operator which converges to in the neighborhood of . The theory states that has a fixed point which solves the approximate problem. It also gives the error estimate between and , without assumptions on the well-posedness of the approximate problem. We apply the unified theory to the finite element approximation of the Schrödinger-Poisson model and obtain optimal error estimate between the numerical solution and the exact solution. Numerical experiments are presented to verify the convergence rates of numerical solutions.

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