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We study the multiplicities of semisimple split characters in tensor product of semisimple split characters of . We prove that these multiplicities are polynomial in q with non-negative integer coefficients and we obtain a criterion for their non-vanishing. We give moreover an interpretation of these polynomials in terms of the counting of the representations of star-shaped quivers, generalizing a previous result of Hausel, Letellier and Rodriguez-Villegas, who linked multiplicities for generic -tuples of semisimple split characters and Kac polynomials.

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