We prove the existence of families of distinct isotopy classes of physical unknots through the key concept of parametrised thickness. These unknots have prescribed length, tube thickness, a uniform bound on curvature, and cannot be disentangled into a thickened round circle by an isotopy that preserves these constraints throughout. In particular, we establish the existence of \emph{gordian unknots}: embedded tubes that are topologically trivial but geometrically locked, confirming a long-standing conjecture. These arise within the space of thin unknots in , and persist across a stratified family , where denotes the tube diameter, or thickness. The constraints on curvature and self-distance fragment the isotopy class of the unknot into infinitely many disconnected components, revealing a stratified structure governed by geometric thresholds. This unveils a rich hierarchy of geometric entanglement within topologically trivial configurations.

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