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For paraxial light beams and electromagnetic fields, the Stokes vector and polarization matrix provide equivalent scalar measures of optical chirality, widely used in linear optics. However, growing interest in non-paraxial fields, with fully three-dimensional polarization components, necessitates an extended framework. Here, we develop a general theory for characterizing optical chirality in arbitrary electromagnetic fields, formulated through extensions of the polarization matrix approach. This framework applies to both near- and far-field optical helicity and chirality. As examples, we demonstrate its relevance to near-zone fields from chiral dipole emission and the focal plane of tightly focused beams.

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