The MAMMOTH-MOSFIRE program is a deep Keck/MOSFIRE K-band spectroscopic follow-up of emission-line galaxies identified in the MAMMOTH-Grism HST/WFC3 G141 slitless spectroscopic survey, targeting the core regions of three most massive galaxy protoclusters at cosmic noon. To introduce this program, we present a comprehensive analysis of the 6584, 6717,6731, and 6300 BPT diagnostics for a unique sample of 43 protocluster member galaxies at , investigating how the overdense environment influences their interstellar medium ionization conditions. We find that, similar to their field counterparts at , protocluster galaxies exhibit a systematic offset in the BPT diagram relative to the local star-forming sequence, but no such offset in the BPT diagram. Notably, we detect significantly elevated / ratios, which can be well reproduced by photoionization models incorporating both regions and low-velocity shocks ( 200 km s). We caution that neglecting shock excitation can bias abundance measurements, leading to an overestimation of nitrogen enrichment. This provides a potential explanation for the long-standing puzzle of enhanced / ratios observed in galaxies. We further suggest that these shocks are likely environmentally driven, e.g., by ram-pressure stripping or tidal interactions, which requires future confirmation through direct observations of features such as stripped gas tails.

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