LaNiO is an antiferromagnetic insulator with a structural resemblance to its cuprate counterpart, LaCuO. However, LaCuO has a Cu or 3 electronic configuration that needs to be hole or electron doped for superconductivity, whereas LaNiO is 3 with divalent Ni. Making a cuprate analog through conventional electron doping is impractical due to the rarity of tetravalent substituents for trivalent La. Here, we propose an alternative route: intercalating topotactical hydrogen, which is possible through electric-field-controlled protonation and transforms LaNiO into a 3 single-band two-dimensional antiferromagnetic Mott insulator analogous to LaCuO. This we find through density-functional theory and dynamical mean-field theory calculations. The furthergoing dynamical vertex approximation predicts that H-LaNiO can host -wave superconductivity under 15% hole doping with a critical temperature above 20,K. Our findings not only suggest a new method for tuning the electronic structure of layered nickelates but also provide theoretical evidence for a new nickelate superconductor, awaiting experimental synthesis.

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