We extend the multireference covariant density functional theory (MR-CDFT) to describe the low-lying states of the odd-mass nucleus S near the neutron magic number with shape coexistence. The wave functions of the low-lying states are constructed as superpositions of configurations with different intrinsic shapes and quantum numbers, projected onto good particle numbers and angular momenta. The MR-CDFT successfully reproduces the main features of the low-energy structure in S. Our results indicate that the ground state, , is predominantly composed of the intruder prolate one-quasiparticle (1qp) configuration . In contrast, the state is identified as a high- isomer, primarily built on the prolate 1qp configuration . Additionally, the state is found to be an admixture dominated by an oblate configuration with , along with a small contribution from a prolate configuration with . These results demonstrate the capability of MR-CDFT to capture the intricate interplay among shape coexistence, -mixing, and isomerism in the low-energy structure of odd-mass nuclei around .

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