We present the first results from MARTA (Measuring Abundances at high Redshift with the T Approach), a programme leveraging ultra-deep, medium-resolution JWST/NIRSpec spectroscopy to probe the interstellar medium (ISM) of star-forming galaxies at . We report detections of one or more auroral lines, including [O III], [O II], [S II] , and [S III] for 16 galaxies in the sample, providing measurements of multiple ionic temperatures. We tested the validity of the T[O II]-T[O III] relation at high redshift considering a total sample of 21 objects including literature data, and obtained a shallower slope than in the low- literature. However, such a slope is consistent with low-redshift data when ultra-low metallicity objects are considered. We assessed the correlation of the T[O II]-T[O III] relationship and its scatter on different physical parameters, finding a mild correlation with the ionisation parameter and radiation field hardness, while no significant correlation with gas density. The location of high-redshift data is also consistent with the low- literature in the T[O II]-T[S II], and T[S III]-T[O III] relations, although this conclusion is limited with low-number statistics. Finally, we leveraged our sample together with a comprehensive compilation of galaxies with [O III] detections from the literature to recalibrate classical strong-line diagnostics at high redshift. MARTA represents a key addition in this space because it provides direct metallicities at moderately high oxygen abundances (12+log(O/H) ).

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