The Born-Oppenheimer approximation is one of the very successful tools for solving the hydrogen atom problem. The experimental discovery of hidden heavy flavor tetraquarks, ( and ), provides great possibilities for the hydrogen-bond-like structure of the Quantum Chromodynamics version. In this work, considering that the colors of and are both , the tetraquark system is formed by color coupling . In order to study the mass splitting caused by the color-spin hyperfine interaction, the color-spin basis vectors of the -wave tetraquark states are appropriately constructed. Then we use the Born-Oppenheimer approximation to calculate the mass spectra of the -wave hidden heavy flavor tetraquark states. The results show that some of the hidden heavy flavor exotic hadrons discovered experimentally can be well explained as this type of hydrogen-bond-like tetraquark structure. In addition, some candidates for tetraquark bound states are predicted and may be compact tetraquark states.

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