We study transverse single spin asymmetries (TSSAs) in back-to-back photon plus jet production in the scattering of unpolarized beams of protons off a transversely polarized proton target as probes of Gluon Sivers Function (GSF). We provide estimates within the region where the imbalance between the transverse momenta of the photon and the jet is much smaller than the average of the transverse momenta i.e. the back-to-back region. The presence of these two scales in the process makes it particularly suitable for applying transverse momentum dependent (TMD) factorization, in contrast to single-scale processes that rely on the generalized parton model approach. We present our preliminary results of the transverse single spin asymmetry for this process at = 200 GeV.

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