The Pólya group of an algebraic number field is the subgroup of the ideal class group generated by the ideal classes of the products of prime ideals of the same norm. If is trivial, then the number field is said to be a Pólya field. In this article, we furnish three families , and of bi-quadratic Pólya fields involving prime numbers and that satisfy certain quadratic residue conditions. It is worthwhile to note that in each of the fields, exactly five primes ramify in and this is the maximum possible number of ramified primes in a Pólya field over . Towards the end of the paper, we discuss about large Pólya groups of the compositums of Shank’s cubic fields and Lehmer’s quintic fields and prove that there are infinitely many such fields with index .

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