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We exhibit a new pre-Lie algebra in the framework of symplectic groupoids and, in turn, introduce a pre-Lie formalism of Butcher trees for the approximation of Hamilton-Jacobi solutions on any symplectic groupoid The impact of this new algebraic approach is twofold. On the geometric side, it yields algebraic operations to approximate Lagrangian bisections of using the Butcher-Connes-Kreimer Hopf algebra and, in turn, aims at a better understanding of the group of Hamiltonian diffeomorphisms of On the computational side, we define a new class of Poisson integrators for Hamiltonian dynamics on Poisson manifolds.

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