Turbulence is a complex phenomenon that plays a critical role in the interstellar medium (ISM). Previous simulations and observations show that the probability density function (PDF) of gas density in isothermal and compressible systems under turbulence exhibits a near lognormal shape, with a strong empirical relation between the variance () and Mach number (). In this work, we aim to explain the - relation and the deviation from the lognormal shape from a thermodynamic and cascading perspective. By introducing a virtual dissipation process, during which turbulent entropy and structural dissipation are assumed to be coupled, we derive the empirical relation . Additionally, by introducing a delay parameter for the local gas temperature, we derive the deviation from the empirical relation at high . We further argue that the exponential tails of PDFs (on the scale) arise from the convolution of PDF kernels, which can be skewed at both the low- and high- ends. Skewness has limited influence on the - relation. Two density-fraction strategies–the mass-fraction and volume-fraction approaches–are introduced to explain the physical origins of the low- and high- skewed PDF kernels. These two types of PDF kernels are dual to each other and exhibit highly symmetric mathematical structures. We speculate that the high- skewed PDF kernels are physical and may be analogous to the high-density tails of column-density PDFs in molecular clouds, which are influenced by gravity. Inspired by this, we propose a form of an “isothermal” turbulent system that likely favors the volume-fraction strategy.

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