We study a -state Potts model on the square grid when at the point of its (discontinous) transition. This model exhibits exactly extremal Gibbs measures: ordered (monochromatic) and one disordered (free). The current work deals with the Dobrushin order–disorder boundary conditions on a finite box. Our main result is that this interface is a well-defined object, has fluctuations, and converges to a Brownian bridge under diffusive scaling. The same holds also for the corresponding FK-percolation model for all . Our proofs rely on a coupling between FK-percolation, the six-vertex model, and the random-cluster representation of an Ashkin–Teller model (ATRC), and on a detailed study of the latter. The coupling relates the interface in FK-percolation to a long subcritical cluster in the ATRC model. For this cluster we develop a ``renewal picture’’ à la Ornstein-Zernike. This is based on fine mixing properties of the ATRC model that we establish using the link to the six-vertex model and its height function. Along the way, we derive various properties of the Ashkin-Teller model, such as Ornstein-Zernike asymptotics for its two-point function. In a companion work, we provide a detailed study of the Potts model under order-order Dobrushin conditions. We show emergence of a free layer of width between the two ordered phases (wetting) and establish convergence of its boundaries to two Brownian bridges conditioned not to intersect.

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