In this paper, we study Bass-Serre theory from the perspectives of -algebras and topological dynamics. In particular, we investigate the actions of fundamental groups of graphs of groups on their Bass-Serre trees and the associated boundaries, through which we identify new families of -simple groups including certain tubular groups, fundamental groups of certain graphs of groups with one vertex group acylindrically hyperbolic and outer automorphism groups of Baumslag-Solitar groups. In addition, we study -dimensional Generalized Baumslag-Solitar () groups. We first recover a result by Minasyan and Valiunas on the characterization of -simplicity for groups and identify new -simple groups including the Leary-Minasyan group. These -simple groups also provide new examples of -selfless groups and highly transitive groups. Moreover, we demonstrate that natural boundary actions of these -simple fundamental groups of graphs of groups give rise to the new purely infinite crossed product -algebras.

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