This paper investigates an initial boundary value problem for the relaxed one-dimensional compressible Navier-Stokes-Fourier equations. By transforming the system into Lagrangian coordinates, the resulting formulation exhibits a uniform characteristic boundary structure. We first construct an approximate system with non-characteristic boundaries and establish its local well-posedness by verifying the maximal nonnegative boundary conditions. Subsequently, through the construction of a suitable weighted energy functional and careful treatment of boundary terms, we derive uniform a priori estimates, thereby proving the global well-posedness of smooth solutions for the approximate system. Utilizing these uniform estimates and standard compactness arguments, we further obtain the existence and uniqueness of global solutions for the original system. In addition, the global relaxation limit is established. The analysis is fundamentally based on energy estimates.

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