Understanding the transition from atomic gas to molecular gas is critical to explain the formation and evolution of molecular clouds. However, the gas phases involved, cold HI and CO-dark molecular gas, are challenging to directly observe and physically characterize. We observed the Cygnus X star-forming complex in carbon radio recombination lines (CRRLs) at 274–399 MHz with the Green Bank Telescope at 48’ (21 pc) resolution. Of the 30 deg surveyed, we detect line-synthesized C273 emission from 24 deg and produce the first large-area maps of low-frequency CRRLs, which likely originate in CO-dark molecular gas. The morphology of the C273 emission reveals arcs, ridges, and extended possibly sheet-like gas which are often on the outskirts of CO emission. We find a correlation between velocity-integrated C273 and the 8 m intensity with a power-law slope of . We interpret the relation as the dependence of cool dark gas emission on the FUV radiation field, . We determine the typical angular separation between C273 and CO emission to be 12 pc. Velocity differences between C273 and CO are apparent throughout the region and have a typical value of 2.9 km s. We estimate gas densities of cm with a nominal cm in the C/H layer. The evolution of the C273 gas seems to be dominated by turbulent pressure, with a characteristic timescale to form H of about 2.6 Myr. These observations underline the richness of low-frequency CRRLs to provide revelatory insights into the characteristics of (CO-)dark gas and the evolution of molecular gas.

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