White dwarf-main sequence (WDMS) binary systems are essential probes for understanding binary stellar evolution and play a pivotal role in constraining theoretical models of various transient phenomena. In this study, we construct a catalog of WDMS binaries using Gaia DR3’s low-resolution BP/RP (XP) spectra. Our approach integrates a model-independent neural network for spectral modelling with Gaussian Process Classification to accurately identify WDMS binaries among over 10 million stars within 1 kpc. This study identify approximately 30,000 WDMS binary candidates, including ~1,700 high-confidence systems confirmed through spectral fitting. Our technique is shown to be effective at detecting systems where the main-sequence star dominates the spectrum - cases that have historically challenged conventional methods. Validation using GALEX photometry reinforces the reliability of our classifications: 70% of candidates with an absolute magnitude exhibit UV excess, a characteristic signature of white dwarf companions. Our all-sky catalog of WDMS binaries expands the available dataset for studying binary evolution and white dwarf physics and sheds light on the formation of WDMS.

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