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We prove necessary and sufficient conditions for the existence of non-trivial Steenrod actions on the mod- cohomology of 4-dimensional toric orbifolds. As applications, the stable homotopy type and the gauge groups of a -dimensional toric orbifold are determined, a partial solution to the cohomological rigidity problem for -dimensional toric orbifolds is provided, and, in the smooth case, a combinatorial criterion is established for when the toric orbifold is spin.

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