We propose to use the ordinal pattern transition (OPT) entropy measured at sentinel central nodes as a potential predictor of explosive transitions to synchronization in networks of various dynamical systems with increasing complexity. Our results demonstrate that the OPT entropic measure surpasses traditional early warning signals (EWS) measures and could be valuable to the tools available for predicting critical transitions. In particular, we investigate networks of diffusively coupled phase oscillators and chaotic Rössler systems. As maps, we consider a neural network of Chialvo maps coupled in star and scale-free configurations. Furthermore, we apply this measure to time series data obtained from a network of electronic circuits operating in the chaotic regime.

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