Critical phenomena on scale-free networks with a degree distribution exhibit rich finite-size effects due to its structural heterogeneity. We systematically study the finite-size scaling of percolation and identify two distinct crossover routes to mean-field behavior: one controlled by the degree exponent , the other by the degree cutoff , where is the system size and is the cutoff exponent. Increasing or decreasing suppresses heterogeneity and drives the system toward mean-field behavior, with logarithmic corrections near the marginal case. These findings provide a unified picture of the crossover from heterogeneous to homogeneous criticality. In the crossover regime, we observe rich finite-size phenomena, including the transition from vanishing to divergent susceptibility, distinct exponents for the shift and fluctuation of pseudocritical points, and a numerical clarification of previous theoretical predictions.

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