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We study the spectrum of the Dirichlet to Neumann operator of the two-sphere associated to a Schrödinger operator in the unit ball. The spectrum forms clusters of size around the sequence of natural numbers , and we compute the first three terms in the asymptotic distribution of the eigenvalues within the clusters, as (band invariants). There are two independent aspects of the proof. The first is a study of the Berezin symbol of the Dirichlet to Neumann operator, which arises after one applies the averaging method. The second is the use of a symbolic calculus of Berezin-Toeplitz operators on the manifold of closed geodesics of the sphere.

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