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We prove that each snake module of the quantum Kac-Moody algebra of type admits a Langlands dual representation, as conjectured by Frenkel and Hernandez (Lett. Math. Phys. (2011) 96:217-261). Furthermore, we establish an explicit formula, called the Langlands branching rule, which gives the multiplicities in the decomposition of the character of a snake module of the quantum Kac-Moody algebra of type into a sum of characters of irreducible representations of its Langlands dual algebra.

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