In this article, we provide a comprehensive characterization of invariants of classical Lie superalgebras from the super-analog of the Schur-Weyl duality in a unified way. We establish -invariants of the tensor algebra , the supersymmetric algebra , and the universal enveloping algebra of a classical Lie superalgebra corresponding to every element in centralizer algebras and their relationship under supersymmetrization. As a byproduct, we prove that the restriction on of the projection from to is surjective, which enables us to determine the generators of the center except for . Additionally, we present an alternative algebraic proof of the triviality of . The key ingredient involves a technique lemma related to the symmetric group and Brauer diagrams.

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