In this paper, we construct a categorical solution of the Yang-Baxter equation, i.e. is a small category and is an invertible functor satisfying where is the product category. First, the notion of Rota-Baxter operators on crossed modules of Lie groups is defined and its various properties are established. Then, we use Rota-Baxter operators on crossed modules of Lie groups to construct categorical solutions of the Yang-Baxter equation. We also study the Rota-Baxter operators on crossed modules of Lie algebras which are infinitesimals of Rota-Baxter operators on crossed modules of Lie groups, they can give connections on manifolds. Finally, we study the integration of Rota-Baxter operators on crossed modules of Lie algebras and the differentials of Rota-Baxter operators on crossed modules of Lie groups.

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