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The Tsallis entropy, which possesses non-extensive property, is derived from the first principle employing the non-extensive Hamiltonian or the -deformed Hamiltonian with the canonical ensemble assumption in statistical mechanics. Here, the -algebra and properties of -deformed functions are extensively used throughout the derivation. Consequently, the thermodynamic quantities, e.g. internal energy and Helmholtz free energy, are derived and they inheritly exhibit the non-extensiveness. From this intriguing connection between Tasllis entropy and the -deformed Hamiltonian, the parameter encapsulates the intrinsic degree of non-extensivity for the thermodynamic systems.

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