The Polyak-Lojasiewicz (PL) constant of a function characterizes the best exponential rate of convergence of gradient flow for , uniformly over initializations. Meanwhile, in the theory of Markov diffusions, the log-Sobolev (LS) constant plays an analogous role, governing the exponential rate of convergence for the Langevin dynamics from arbitrary initialization in the Kullback-Leibler divergence. We establish a new connection between optimization and sampling by showing that the low temperature limit of the LS constant of is exactly the PL constant of , under mild assumptions. In contrast, we show that the corresponding limit for the Poincaré constant is the inverse of the smallest eigenvalue of at the minimizer.

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