This work explores the implications of the exclusivity principle (EP) in the context of quantum and postquantum correlations. We first establish a key technical result demonstrating that given the set of correlations for a complementary experiment, the EP restricts the maximum set of correlations for the original experiment to the antiblocking set. Based on it, we can prove our central result: if all quantum behaviors are accessible in Nature, the EP guarantees that no postquantum behaviors can be realized. This can be seen as a generalization of the result of B. Amaral et al. [Phys. Rev. A 89, 030101® (2014)], to a wider range of scenarios. It also provides novel insights into the structure of quantum correlations and their limitations.

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