The - spin chain is one of the canonical models of quantum magnetism, and has long been known to host a critical antiferromagnetic phase with power-law decay of spin correlations. We show in this Letter that there are, in fact, distinct critical antiferromagnetic phases, where the roles of the local dimer field and its dual field are interchanged: the Affleck-Haldane' phase near the Heisenberg point $J_2 = 0$, where the dimer field that parametrises local singlet order is gapless and part of a joint $O(4)$ Néel-singlet order parameter; and the Zirnbauer’ phase which appears at sufficiently large ferromagnetic , where the dimer field is gapped out and its field – the instanton density of the Néel field – is critical instead. The phases are so-named because each realises one of the competing pictures for how the non-linear sigma model with a topological theta term renormalises to the Wess-Zumino-Witten model. We support these predictions with density matrix renormalisation group calculations.

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