We report on the masses and hyperfine structure of ground and isomeric states in Ag isotopes, measured with the phase-imaging ion-cyclotron-resonance technique (PI-ICR) with the JYFLTRAP mass spectrometer and the collinear laser spectroscopy beamline at the Ion Guide Isotope Separator On-Line (IGISOL) facility, Jyväskylä, Finland. We measured the masses and excitation energies, electromagnetic moments, and charge radii, and firmly established the nuclear spins of the long-lived states. A new isomer was discovered in Ag and the half-lives of Ag long-lived states were reevaluated. We unambiguously pinned down the level ordering of all long-lived states, placing the inversion of the and states at . Lastly, we compared the electromagnetic moments of each state to empirical single-particle moments to identify the dominant configuration where possible.

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