We are concerned with qualitative properties of positive solutions to the following coupled Sobolev critical Schrödinger equations subject to the mass constraints and , where, and is the Sobolev critical exponent. The main purpose of this paper is focused on the mass mixed case, i. e., . For some suitable small , we show that the above system admits two positive solutions, one of which is a local minimizer, and another one is a mountain pass solution. Moreover, as , asymptotic behaviors of solutions are also considered. Our result gives an affirmative answer to a Soave’s type open problem raised by Bartsch {\it et al.} (Calc. Var. Partial Differential Equations 62(1), Paper No. 9, 34, 2023).

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