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The np pair in the spin-singlet state is treated as a Cooper np-pair within the extension of the Nambu-Jona-Lasinio model of light nuclei, describing the deuteron as a Cooper np-pair in the spin-triplet state. For the Cooper np-pair in the spin-singlet state we compute the binding energy and express the S-wave scattering length of np scattering in the spin-singlet state in terms of the binding energy. The theoretical value of the S-wave scattering length of np scattering agrees well with the experimental data.

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