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We have studied via in-beam -ray spectroscopy Po and Po, which are the first neutron-deficient Po isotopes to exhibit a collective low-lying structure. The ratios of yrast state energies and the E2 branching ratios of transitions from non-yrast to yrast states are indicative of a low-lying vibrational structure. The onset of collective motion in these isotopes can be attributed to the opening of the neutron i orbital at N112 and the resulting large overlap between the two valence protons in the h orbital and the valence neutrons in the i orbital.

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