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A Large Ion Collider Experiment - ALICE will become operational with the startup of the Large Hadron Collider - LHC at the end of 2007. One focus of the physics program is the measurement of quarkonia in proton-proton and lead-lead collisions. Quarkonia states will be measured in two kinematic regions and channels: di-muonic decays will be measured in the forward region by the muon arm, the central part of the detector will measure di-electronic decays. The presented studies show the expected performance of the di-electron measurement in proton-proton and central lead-lead collisions.

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