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The possible occurence of highly deformed configurations is investigated in the Ca and Ni di-nuclear systems as formed in the Si+C,Si reactions by using the properties of emitted light charged particles. Inclusive as well as exclusive data of the heavy fragments and their associated light charged particles have been collected by using the {\sc ICARE} charged particle multidetector array. The data are analysed by Monte Carlo CASCADE statistical-model calculations using a consistent set of parameters with spin-dependent level densities. Significant deformation effects at high spin are observed as well as an unexpected large Be cluster emission of a binary nature.

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