Recently, Floquet topological matter has attracted significant attention for its potential to reveal novel topological phases inaccessible in static systems. In this paper, we investigate the effect of a time-periodic driving on the five-dimensional (5D) normal insulators. We show that the time-periodic driving can induce a topological phase transition from a (time reversal combined with space inversion) symmetry-preserving normal insulator to a 5D Floquet topological semimetal with emergent Yang monopoles characterized by the second Chern number. Additionally, we show that this time-periodic driving can also lead to a topological phase transition from a symmetry-breaking normal insulator to a 5D Floquet topological semimetal with a Hopf link formed by Weyl surfaces. Besides, further increasing the strength of the time-periodic driving, the two 5D Floquet topological semimetal phases are transformed into the 5D Floquet Chern insulators. Our paper is helpful for future studies in higher dimensional Floquet systems.

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