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For any (unital) exchange ring whose finitely generated projective modules satisfy the separative cancellation property ($A\oplus A\cong A\oplus B\cong B\oplus BA\cong B$), it is shown that all invertible square matrices over can be diagonalized by elementary row and column operations. Consequently, the natural homomorphism is surjective. In combination with a result of Huaxin Lin, it follows that for any separative, unital C*-algebra with real rank zero, the topological is naturally isomorphic to the unitary group modulo the connected component of the identity. This verifies, in the separative case, a conjecture of Shuang Zhang.

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